Special Issue on Ruthenium Complexes.
نویسندگان
چکیده
The organic chemistry of ruthenium has been one of the most vigorously growing research areas over the past decades. Considerable effort has been extended towards the design and application of a broad series of ruthenium complexes, which culminated with the development by Ryoji Noyori (2001 Nobel Prize for Chemistry) of chiral ruthenium catalysts for stereoselective hydrogenation reactions [1], and the discovery by Robert H. Grubbs (2005 Nobel Prize for Chemistry) of well-defined ruthenium- benzylidene catalysts for olefin metathesis [2] [...].
منابع مشابه
Editorial of Special Issue Ruthenium Complex: The Expanding Chemistry of the Ruthenium Complexes.
Recent trends in Ru complex chemistry are surveyed with emphasis on the development of anticancer drugs and applications in catalysis, polymers, materials science and nanotechnology.
متن کاملSynthesis, Characterization, Electrochemical and Spectroelectrochemical Properties of Ruthenium(II) Complexes Containing Phenylcyanamide Ligands and Effect of the Inner- Sphere on the Ru-NCN Chromophore
[Ru(terpy)(bpy)(L)]PF6 complexes, where terpy is 2,2΄:6′,2″– terpyridine, bpy is 2,2΄ - bipyridine and L is monoanions of 4 - bromophenylcyanamide (4 - Brpcyd), 4-methoxyphenylcyanamide (4 - MeOPcyd), 2, 4 - dibromophenylcyanamide (2,4 - Br2pcyd), 2,4-dimethylphenylcyanamide (2,4 - Me2pcyd), 2 - methylphenylcyanamide (2 ...
متن کاملMolecular Implementations of Quantum-dot Cellular Automata: the Vibronic Problem in Mixed-valence Tetra-ruthenium Species
Here we report the evaluation of the electronic and vibronic levels of mixedvalence tetra-ruthenium (2Ru(II)+2Ru(III)) systems assembled as two coupled Creutz-Taube complexes for which possible molecular implementations of quantumdot cellular automata was proposed. In this view the main theoretical issue is related to the vibronic localization of the two holes whose positions are able encode in...
متن کاملReactivity of ruthenium vinylidene complexes containing indenyl/dppe ligands and unsaturated bonds at Cδ with trimethylsilyl azide.
This study presents a new reaction of cationic vinylidene complexes with Me₃SiN₃ (TMSN₃), which yields N-coordinated nitrile complexes 3. Treatment of a ruthenium acetylide precursor containing indenyl and dppe ligands with a series of organic halides produced the corresponding vinylidene complexes 2 in good yield. Further reaction of 2 with TMSN₃ at room temperature produced N-coordinated ruth...
متن کاملPyrrolyl substituted allenylidene complexes of ruthenium.
Pyrrolyl and indolyl substituted allenylidene complexes of ruthenium have been prepared from the trapping of cationic trans-[Cl(dppm)(2)Ru=C=C=C=CH(2)](+) with various pyrroles or N-methylindole. The reaction is rationalized as involving regioselective attack of the organometallic electrophile on the electron-rich heterocycle followed by proton migration to the terminal =CH(2) entity of the int...
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ورودعنوان ژورنال:
- Molecules
دوره 22 2 شماره
صفحات -
تاریخ انتشار 2017